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| 22:00 | Jessica Bouzas Maneiro - Beatriz Haddad Maia | |
| 20:30 | Mattia Bellucci - Gabriel Diallo | |
| 22:30 | Matteo Berrettini - Adrian Mannarino | |
| 22:00 | Jenson Brooksby - Alexei Popyrin | |
| 20:30 | Mattia Bellucci - Gabriel Diallo | |
| 22:00 | Jessica Bouzas Maneiro - Beatriz Haddad Maia | |
| 22:30 | Matteo Berrettini - Adrian Mannarino | |
| 20:30 | Zizou Bergs - Jan-Lennard Struff | |
| 20:00 | Daniel Altmaier - Miomir Kecmanovic | |
| 20:30 | Zizou Bergs - Jan-Lennard Struff | |
| 22:00 | Jenson Brooksby - Alexei Popyrin | |
| 20:00 | Daniel Altmaier - Miomir Kecmanovic | |
| all times GMT +2 | ||